A tandem photoelectrochemical cell based on Cu2-xTe nanocrystals for solar energy conversion to hydrogen

نویسندگان

چکیده

In this work we present the design, assembly and characterization of a tandem photoelectrochemical (PEC) cell based on two different crystallographic phases sub-stoichiometric copper telluride nanocrystals (NCs). The first one, pseudo-cubic phase, pc-Cu2-xTe, is characterized by positive photocurrents, while second hexagonal h-Cu2-xTe, favors negative ones. Taking advantage optoelectronic properties Cu2-xTe structures, prepared PEC composed hybrid pc-Cu2-xTe/TiO2 photoanode, with TiO2 acting as light absorber electron selective layer, h-Cu2-xTe/CuI photocathode, CuI behaving photo-absorber hole layer. shows photocurrent density ∼0.5 mA/cm2 when measured in 2-electrode configuration without any co-catalyst. Finally, to test performance for hydrogen evolution reaction (HER), thin film Pt was deposited top photocathode ∼7 μmol were obtained at 0.6 V 1-h experiment, reaching 1 no losses.

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ژورنال

عنوان ژورنال: Solar Energy Materials and Solar Cells

سال: 2023

ISSN: ['0927-0248', '1879-3398']

DOI: https://doi.org/10.1016/j.solmat.2022.112050